Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 136, Issue 40, Pages 13987-13990Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja5075294
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- Department of Science and Technology (DST), India
- DST
- CSIR
- UGC
- IITK
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The utility and selectivity of the catalyst [Ru(COD)(L-1)Br-2] (1) bearing a fused pi-conjugated imidazo[1,2-a][1,8]naphthyridine-based abnormal N-heterocyclic carbene ligand L-1 is demonstrated toward selective oxidation of C-C bonds to aldehydes and C C bonds to alpha-diketones in an EtOAc/CH3CN/H2O solvent mixture at room temperature using a wide range of substrates, including highly functionalized sugar- and amino acid-derived compounds.
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