Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 135, Issue 35, Pages 12976-12979Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja406893y
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Funding
- Japan Society for the Promotion of Science (JSPS) through a Funding Program for Next-Generation World-Leading Researchers
- Japanese Ministry of Education, Culture, Sports, Science and Technology (MEXT)
- JSPS
- Grants-in-Aid for Scientific Research [12J04743, 25104004] Funding Source: KAKEN
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A novel M2L2 molecular tube capable of binding fullerene C-60 was synthesized from bispyridine ligands with embedded anthracene panels and Ag(I) hinges. Unlike previous molecular cages and capsules, this open-ended tubular host can accommodate a single molecule of various C-60 derivatives with large substituents. The fullerene guest can then be released by using the ideal, noninvasive external stimulus, light.
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