Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 135, Issue 31, Pages 11481-11484Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja4052685
Keywords
-
Categories
Funding
- 973 Program [2012CB725302]
- National Natural Science Foundation of China [21025206, 21272180]
- Program for Changjiang Scholars and Innovative Research Team in University [IRT1030]
- Research Fund for the Doctoral Program of Higher Education of China [20120141130002]
Ask authors/readers for more resources
An unprecedented dioxygen-triggered oxidative radical process was explored using dioxygen as the solely terminal oxidant, realizing aerobic oxidaitve difunctionalization of terminal alkynes toward beta-keto sulfones with high selectivity. Operando IR experiments revealed that pyridine not only acts as a base to successfully surpress ATRA (atom transfer radical addition) process, but also plays a vital role in reducing the activity of sulfinic acids.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available