Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 135, Issue 15, Pages 5505-5508Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja400311h
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Funding
- European Research Council under the European Community's Seventh Framework Program (FP7)/ERC Grant [25936]
- NRW Graduate School of Chemistry
- Alexander von Humboldt Foundation
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A room-temperature intramolecular oxy- and aminoarylation of alkenes with aryldiazonium salts has been developed using a novel gold and photoredox dual-catalytic system. The compatibility of these two catalytic modes has been established for the first time and demonstrates the potential of this system as a method to expand the scope of nucleophilic addition reactions to carbon-carbon multiple bonds.
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