4.8 Article

Combining Gold and Photoredox Catalysis: Visible Light-Mediated Oxy- and Aminoarylation of Alkenes

Journal

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 135, Issue 15, Pages 5505-5508

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ja400311h

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Funding

  1. European Research Council under the European Community's Seventh Framework Program (FP7)/ERC Grant [25936]
  2. NRW Graduate School of Chemistry
  3. Alexander von Humboldt Foundation

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A room-temperature intramolecular oxy- and aminoarylation of alkenes with aryldiazonium salts has been developed using a novel gold and photoredox dual-catalytic system. The compatibility of these two catalytic modes has been established for the first time and demonstrates the potential of this system as a method to expand the scope of nucleophilic addition reactions to carbon-carbon multiple bonds.

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