Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 135, Issue 29, Pages 10630-10633Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja405742y
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Funding
- National Basic Research Program of China [2012CB215306, 2013CB932800]
- NNSFC [21172209]
- CAS [KJCX2-EW-J02]
- China Postdoctoral Science Foundation [2011M500289, 2012T50078]
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A Rh-catalyzed directed C-H cyanation reaction was developed for the first time as a practical method for the synthesis of aromatic nitriles. N-Cyano-N-phenyl-p-toluenesulfonamide, a user-friendly cyanation reagent, was used in the transformation. Many different directing groups can be used in this C-H cyanation process, and the reaction tolerates a variety of synthetically important functional groups.
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