Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 135, Issue 28, Pages 10270-10273Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja4044642
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Funding
- National Science Foundation [DMR-0846958]
- ACS Petroleum Research Fund [50635-UR10]
- Direct For Mathematical & Physical Scien
- Division Of Materials Research [0846958] Funding Source: National Science Foundation
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Reported here are the new concept of utilizing open metal sites (OMSs) for architectural pore design and its practical implementation. Specifically, it is shown here that OMSs can be used to run extended hooks (isonicotinates in this work) from the framework walls to the channel centers to effect the capture of single metal ions or dusters, with the concurrent partitioning of the large channel spaces into multiple domains, alteration of the host-guest charge relationship and associated guest-exchange properties, and transfer of OMSs from the walls to the channel centers. The concept of the extended hook, demonstrated here in the multicomponent dual-metal and dual-ligand system, should be generally applicable to a range of framework types.
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