Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 135, Issue 25, Pages 9330-9333Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja404616c
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Funding
- MEXT [22107006, 2206]
- JSPS [24750107]
- Grants-in-Aid for Scientific Research [24750107, 22107006] Funding Source: KAKEN
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Alkyl vinyl ethers and isobutylene oxide were concurrently copolymerized through cationic vinyl addition and ring opening using B(C6F5)(3) as a catalyst. NMR analyses and acid hydrolysis of the products demonstrated that the copolymerization successfully proceeded through crossover reactions between vinyl and cyclic monomers to yield multiblock-like copolymers. Appropriate catalyst and monomer combinations with suitable reactivities were key for copolymerization.
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