Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 135, Issue 32, Pages 11720-11723Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja405495u
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Funding
- DTRA [HDTRA1-10-1-0023]
- Weinberg College of Arts and Sciences, Northwestern University
- NSF-NSEC
- NSF-MRSEC
- Keck Foundation
- state of Illinois
- Northwestern University
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An Al(porphyrin) functionalized with a large axial ligand was incorporated into a porous organic polymer (POP) using a cobalt-catalyzed acetylene trimerization strategy. Removal of the axial ligand afforded a microporous POP that is catalytically active in the methanolysis of a nerve agent simulant. Supercritical CO2 processing of the POP dramatically increased the pore size and volume, allowing for significantly higher catalytic activities.
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