4.8 Article

Postsynthesis Modification of a Porous Coordination Polymer by LiCl To Enhance H+ Transport

Journal

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 135, Issue 12, Pages 4612-4615

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ja3122872

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Funding

  1. Japan Science and Technology Agency PRESTO program
  2. Japan Society for the Promotion of Science (JSPS)
  3. Japan Science and Technology Agency ERATO program
  4. World Premier International Research Initiative (WPI), MEXT, Japan
  5. Grants-in-Aid for Scientific Research [23750155] Funding Source: KAKEN

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A Ca2+ porous coordination polymer with ID channels was functionalized by the postsynthesis addition of LiCl to enhance the H+ conductivity. The compound showed over 10(-2) S cm(-1) at 25 degrees C and 20% relative humidity. Pulse-field gradient NMR elucidated that the fast H+ conductivity was achieved by the support of Li+ ion movements in the channel.

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