Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 135, Issue 50, Pages 18730-18733Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja409748m
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Funding
- JSPS KAKENHI [24229011]
- Takeda Science Foundation
- Asahi Glass Foundation
- Daiichi-Sankyo Foundation of Life Sciences
- Mochida Memorial Foundation
- Tokyo Biochemical Research Foundation
- Foundation NAGASE Science Technology Development
- Yamada Science Foundation
- Sumitomo Foundation
- JSPS [25713001, 24850005]
- Grants-in-Aid for Scientific Research [25713001, 24850005] Funding Source: KAKEN
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Borylzincate was generated in situ from dialkylzinc, diboron, and metal alkoxide. Model DFT calculations showed that although the formation of borylzincate is kinetically favorable, it is thermodynamically unfavorable. Therefore, we designed a successive reaction sequence that would provide a compensating energy gain. This enabled Zn-catalyzed borylation of aryl halides and borylzincation of benzynes and terminal alkyne from diborons without the need for any cocatalyst.
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