4.8 Article

How Far Can We Push Polymer Architectures?

Journal

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 135, Issue 31, Pages 11421-11424

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ja400890v

Keywords

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Funding

  1. Dutch Ministry of Education, Culture and Science (Gravity program) [024.001.035]
  2. European Research Council [246829]
  3. National Science Foundation [DMR-09-69301, DMR-1122483]
  4. CRP Consortium at Carnegie Mellon University
  5. Division Of Materials Research
  6. Direct For Mathematical & Physical Scien [0906985, 969301] Funding Source: National Science Foundation

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We here report the synthesis and characterization of a complex polymeric architecture based on a block copolymer with a cylindrical brush block and a single-chain polymeric nanoparticle block folded due to strong intramolecular hydrogen-bonds. The self-assembly of these constructs on mica surfaces was studied with atomic force microscopy, corroborating the distinct presence of block copolymer architectures.

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