Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 135, Issue 9, Pages 3403-3406Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja400962h
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Funding
- University of Michigan Department of Chemistry
- NSF [CHE-0840456]
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A frustrated Lewis pair accessory functionality is positioned in the secondary coordination sphere of a terpyridine ligand (Tpy(BN) = 6-morpholino-2,2':6',2 ''-terpyridine-6 ''-boronic acid pinacol ester) to promote directed Lewis acid/base interactions. Following metalation with VCl3, the utility of the metal Lewis acid/base triad (LABT) is highlighted with N2H4 as a cooperatively coordinated substrate, affording the first eta(2)-[N2H3](-) vanadium complex.
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