Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 135, Issue 50, Pages 18726-18729Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja409672w
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Funding
- JSPS
- MEXT, Japan
- Grants-in-Aid for Scientific Research [12J08866] Funding Source: KAKEN
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Unprecedented direct acceptorless dehydrogenation of C-C single bonds adjacent to functional groups to form alpha,beta-unsaturated compounds has been accomplished by using a new class of group 9 metal complexes. Metal-ligand cooperation operated by the hydroxycyclopentadienyl ligand was proposed to play a major role in the catalytic transformation.
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