Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 136, Issue 1, Pages 24-27Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja409974b
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Funding
- international PhD program Catalysis for Sustainable Synthesis (CaSuS)
- DFG [Me 1313/9-1]
- MINECO ERA-Chem
- [CTQ-2010-21497]
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A new powerful and oxidatively rugged pyrazolate-based water oxidation catalyst of formula {[Ru-II(py-SO3)(2)(H2O)](2)(mu-Mebbp)}(-), 1(H2O)(2)(-), has been prepared and thoroughly characterized spectroscopically and electrochemically. This new catalyst has been conceived based on a specific ligand tailoring design, so that its performance has been systematically improved. It was also demonstrated how subtle ligand modifications cause a change in the O-O bond formation mechanism, thus revealing the close activation energy barriers associated with each pathway.
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