Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 135, Issue 6, Pages 2140-2143Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja312487r
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- Netherlands Organization for Scientific Research (NWO-CW)
- National Research School Catalysis (NRSC-C)
- Spanish Ministry of Science and Innovation (MICINN)
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A Cu(I)-phosphoramidite-based catalytic system that allows asymmetric allyl-allyl cross-coupling with high enantioselectivity is reported. This transformation tolerates a large variety of functionalized substrates. The versatility of this new reaction is illustrated in the catalytic asymmetric synthesis of the Martinelline alkaloids chromene derivative core.
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