4.8 Article

Ligand Conjugation of Chemically Exfoliated MoS2

Journal

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 135, Issue 12, Pages 4584-4587

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ja310929s

Keywords

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Funding

  1. National Cancer Institute Center for Cancer Nanotechnology Excellence (CCNE) initiative at Northwestern University [U54CA119341]
  2. National Science Foundation [DMR CAREER 0955612]
  3. Alfred P. Sloan Research Foundation
  4. Basic Science Research Program through the National Research Foundation of Korea
  5. MEST [2012-000181]
  6. US DHS
  7. National Research Foundation of Korea [2009-0081359] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
  8. Direct For Mathematical & Physical Scien
  9. Division Of Materials Research [0955612] Funding Source: National Science Foundation

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MoS2 is a two-dimensional material that is gaining prominence due to its unique electronic and chemical properties. Here, we demonstrate ligand conjugation of chemically exfoliated MoS2 using thiol chemistry. With this method, we modulate the zeta-potential and colloidal stability of MoS2 sheets through ligand designs, thus enabling its usage as a selective artificial protein receptor for beta-galactosidase. The facile thiol functionalization route opens the door for surface modifications of solution processable MoS2 sheets.

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