4.8 Article

Preparation and Exceptional Lithium Anodic Performance of Porous Carbon-Coated ZnO Quantum Dots Derived from a Metal-Organic Framework

Journal

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 135, Issue 20, Pages 7394-7397

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ja311550t

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Funding

  1. National Research Foundation of Korea (NRF)
  2. Korean Government (MEST) [2010-0029244, 2012-0000580]
  3. National Research Foundation of Korea [R31-2012-000-10075-0, 2010-0029244] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)

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Hierarchically porous carbon-coated ZnO quantum dots (QDs) (similar to 3.5 nm) were synthesized by a one-step controlled pyrolysis of the metal-organic framework IRMOF-1. We have demonstrated a scalable and facile synthesis of carbon-coated ZnO QDs without agglomeration by structural reorganization. This unique microstructure exhibits outstanding electrochemical performance (capacity, cyclability, and rate capability) when evaluated as an anode material for lithium ion batteries.

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