4.8 Article

Mechanistic Insights and Kinetic Analysis for the Oxidative Hydroxylation of Arylboronic Acids by Visible Light Photoredox Catalysis: A Metal-Free Alternative

Journal

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 135, Issue 36, Pages 13286-13289

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ja406311g

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Funding

  1. Natural Sciences and Engineering Research Council of Canada
  2. Canadian Foundation for Innovation
  3. Canada Research Chairs program

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The photocatalytic hydroxylation of boronic acids with methylene blue as photosensitizer proceeds with high efficiency. Detailed time-resolved studies of the relevant rate constants provide a clear mechanistic understanding of excited-state processes and guided the selection of the photocatalyst and the optimization of experimental conditions.

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