Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 135, Issue 9, Pages 3307-3310Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja312087x
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Funding
- NSF [CHE 1151364]
- National Institute of General Medical Sciences of the NIH [P20GM103541]
- NIH [NSF MIR 0421224, NIH P20 RR017716]
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [1151364, 1229234] Funding Source: National Science Foundation
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We have developed a stereospecific nickel-catalyzed cross-coupling of benzylic pivalates with arylboroxines. The success of this reaction relies on the use of Ni(cod)(2) as the catalyst and NaOMe as a uniquely effective base. This reaction has broad scope with respect to the arylboroxine and benzylic pivalate, enabling the synthesis of a variety of diarylalkanes and triarylmethanes in good to excellent yields and ee's.
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