Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 135, Issue 26, Pages 9572-9575Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja402694f
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Funding
- Division of Chemical Sciences, Geosciences, and Biosciences, Office of Basic Energy Sciences, U.S. Department of Energy [DE-AC05-00OR22725]
- Division of Scientific User Facilities, Office of Basic Energy Sciences, U.S. Department of Energy
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A template-free synthesis of a hierarchical microporous-mesoporous metal-organic framework (MOF) of zinc(II) 2,5-dihydroxy-1,4-benzenedicarboxylate (Zn-MOF-74) is reported. The surface morphology and porosity of the bimodal materials can be modified by etching the pore walls with various synthesis solvents for different reaction times. This template-free strategy enables the preparation of stable frameworks with mesopores exceeding 15 nm, which was previously unattained in the synthesis of MOFs by the ligand-extension method.
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