4.8 Article

A Microporous Hydrogen-Bonded Organic Framework: Exceptional Stability and Highly Selective Adsorption of Gas and Liquid

Journal

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 135, Issue 32, Pages 11684-11687

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ja403002m

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Funding

  1. Program for New Century Excellent Talents in University [06-0577]
  2. National Natural Science Foundation of China [51268002]
  3. Natural Science Foundation of Jiangxi Province
  4. Science Foundation of the Jiangxi Provincial Office of Education

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An extremely stable hydrogen-bonded organic framework, HOF-8, was fabricated. HOF-8 is not only thermally stable but also stable in water and common organic solvents. More interestingly, desolvated HOF-8 exhibits high CO2 adsorption as well as highly selective CO2 and C6H6 adsorption at ambient temperature.

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