Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 135, Issue 38, Pages 14134-14141Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja404351p
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Funding
- US-NSF [CHE-0957702, CHE-0947088]
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [0957702] Funding Source: National Science Foundation
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A two-dimensional polymer (2DP) based on the dimerization of anthraceno groups arranged in a triptycene motif is reported. A photoinduced polymerization is performed in the crystalline state and gives a lamellar 2DP via a crystal-to-crystal (but not single-crystal to single-crystal) transformation. Solvent-induced exfoliation provides monolayer sheets of the 2DP. The 2DP is considered to be a tiling, a mathematical approach that facilitates structural elucidation.
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