4.8 Article

Iridium-Catalyzed [3+2] Annulation of Cyclic N-Sulfonyl Ketimines with 1,3-Dienes via C-H Activation

Journal

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 135, Issue 6, Pages 2092-2095

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ja311968d

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Funding

  1. MEXT, Japan
  2. Grants-in-Aid for Scientific Research [24550117] Funding Source: KAKEN

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Ir-catalyzed [3 + 2] annulation of cyclic N-sulfonyl ketimines with 1,3-dienes, in which an aryliridium intermediate is formed via C-H activation, gives amino-indane derivatives in high yields with high regio- and diastereoselectivity.

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