Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 135, Issue 13, Pages 5004-5007Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja402477w
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Funding
- Deutsche Forschungsgemeinschaft [DR 14/2]
- Alexander von Humboldt foundation (Sofja Kovalevskaja Program)
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By employing the chelate dicarbene 1, the new chlorogermyliumylidene complex 2 could be synthesized and isolated in 95% yield. Dechlorination of 2 with sodium naphthalenide furnishes the unique cyclic germadicarbene 3 which could be isolated in 45% yield. Compound 3 is the first isolable Ge(0) complex with a single germanium atom stabilized by a dicarbene. Its molecular structure is in accordance with DFT calculations which underline the peculiar electronic structure of 3 with two lone pairs of electrons at the Ge atom.
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