Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 135, Issue 23, Pages 8456-8459Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja4028633
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- Funding Program for World-Leading Innovative R&D on Science and Technology from the Japan Society for the Promotion of Science (JSPS)
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Iron-corrole complexes were found to copolymerize epoxides with CO2. The first iron-catalyzed propylene oxide/CO2 copolymerization has been accomplished. Moreover, the glycidyl phenyl ether (GPE)/CO2 copolymerization with this catalyst provided a crystalline material as a result of the isotactic poly(GPE) moiety.
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