Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 135, Issue 29, Pages 10642-10645Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja405950c
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Funding
- National Institutes of Health [GM46059]
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An orthogonal set of catalyst systems has been developed for the Suzuki-Miyaura coupling of 3,3-disubstituted and 3-monosubstituted allylboronates with (hetero)aryl halides. These methods allow for the highly selective preparation of either the alpha- or the gamma-isomeric coupling product.
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