Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 135, Issue 6, Pages 2136-2139Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja312303a
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Funding
- Danish National Research Foundation
- Danish Council for Independent Research, Natural Sciences
- Marie-Curie ITN SMALL
- Alexander von Humboldt-Foundation
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Using scanning tunneling microscopy, we demonstrate that the 1,3-dipolar cycloaddition between a terminal alkyne and an azide can be performed under solvent-free ultrahigh vacuum conditions with reactants adsorbed on a Cu(111) surface. XPS shows significant degradation of the azide upon adsorption, which is found to be the limiting factor for the reaction.
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