Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 135, Issue 41, Pages 15656-15661Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja4083039
Keywords
-
Categories
Funding
- Alexander von Humboldt Foundation
- DFG [FOR 1806]
- Bavarian State Ministry of Science, Research, and the Arts for the Collaborative Research Network Solar Technologies go Hybrid
Ask authors/readers for more resources
Self-assembly of octahedral Fe(II) ions and linear perylene bisimide (PBI) dyes with 2,2'-bipyridine groups covalently attached at the imide positions quantitatively yields an Fe-4(PBI)(6) tetrahedron by the directional bonding approach. With an edge length of 3.9 nm and estimated internal volume >950 angstrom(3), tetrahedron T is one of the largest M4L6 tetrahedra ever reported. Importantly, many of the desirable photo- and electroactive properties of the PBI ligands are transferred to the nanoscale metallosupramolecule. Tetrahedron T absorbs strongly across the visible spectrum out to 650 nm and exhibits a total of 7 highly reversible electrochemical oxidation and reduction waves spanning a 3.0 V range. This facile cycling of 34 electrons between +18 and -16 charged species is likely enabled due to the porous nature of the tetrahedron that allows the necessary counterions to freely flow in and out of the host. Host-guest encapsulation of C-60 by T in acetonitrile was studied by C-13 NMR spectroscopy, UV-vis spectroscopy, and ESI-MS, confirming that the tetrahedron is a suitable host for large, functional guest molecules.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available