Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 135, Issue 42, Pages 15694-15697Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja407393y
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- Bundesministerium fur Bildung und Forschung (BMBF) [03SF0343D]
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The reaction of Li2S and P2S5 with Li-4[SnS4], a recently discovered, good Li+ ion conductor, yields Li10SnP2S12, the thiostannate analogue of the record holder Li10GeP2S12 and the second compound of this class of superionic conductors with very high values of 7 mS/cm for the grain conductivity and 4 mS/cm for the total conductivity at 27 degrees C. The replacement of Ge by Sn should reduce the raw material cost by a factor of similar to 3.
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