Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 135, Issue 49, Pages 18327-18330Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja410611b
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Funding
- Chinese Academy of Sciences
- National Natural Science Foundation of China [21222203, 21172226, 21133011]
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A new strategy was developed for intercepting the palladium alkyl species generated in Heck reaction via nucleophilic addition prior to the step of migratory insertion, which leads to a new palladium-catalyzed difunctionalization of enol ethers with aminals and alcohols to afford amino acetals. Mechanistic studies suggested that the cationic cyclometalated Pd(II) complex generated by the oxidative addition of aminal to a Pd(0) species was crucial for this unusual transformation.
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