Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 136, Issue 1, Pages 12-15Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja409395y
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Funding
- Max Planck Society
- Deutsche Forschungsgemeinschaft [CRC 951]
- Joint Lab for Structural Research Berlin
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A poly(ionic liquid) with a rather low glass transition temperature of -57 degrees C was synthesized via free radical polymerization of an acrylate-type ionic liquid monomer. It exhibits fluidic behavior in a wide temperature range from room temperature to the threshold of the thermal decomposition. We demonstrate that it could act as a unique type of macromolecular solvent to dissolve various compounds and polymers and separate substances. In addition, this polyelectrolyte could serve successfully as reaction medium for catalysis and colloid particle synthesis. The synergy in the solvation and stabilization properties is a striking character of this polymer to downsize the in situ generated particles.
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