Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 135, Issue 39, Pages 14500-14503Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja4057882
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Funding
- National Basic Research Program [2013CB834503]
- NSFC [91227110, 21221063]
- Ministry of Education of China [20120061110047]
- 111-Project [B06009]
- WVU
- Open Project of SKL of Polymer Physics Chemistry, CAS
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A smart core shell complex is designed to combine a catalytic reaction and automatic separation through remote light control. Here, we present the induced anaphiphilic behavior of a surfactant encapsulated polyoxometalate complex With photoresponsive azobenzene units on the periphery. The reversible phase transfer of the complex shuttle between two incompatible phase termini, driven by a photoisomerization-induced polarity change, further facilitates the separation and recycle of the catalyst.
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