Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 135, Issue 50, Pages 18778-18781Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja4107034
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Funding
- Alfred P. Sloan Foundation
- NIGMS [RO1GM087581]
- NSF [DBI-0619576]
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A nitrile-based template that enables metaselective C-H bond functionalization was developed. The template is applicable to a range of substituted arenes and tolerates a variety of functional groups. The directing group uses a silicon atom for attachment, allowing for a facile introduction/deprotection strategy increasing the synthetic practicality of this template.
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