Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 135, Issue 28, Pages 10338-10341Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja4059316
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Funding
- JST
- ACT-C
- KAKENHI [25713002]
- Grants-in-Aid for Scientific Research [12F02505, 25713002, 25105749] Funding Source: KAKEN
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Catalytic asymmetric hydrophosphonylation of aromatic and aliphatic N-thiophosphinoyl ketimines with dialkyl phosphite was efficiently promoted by as little as 0.5 mol% of catalyst loading at ambient temperature. The catalyst can be recovered for repeated use, and facile removal of the thiophosphinoyl group allowed for ready access to the phosphonic acid analogue of enantioenriched alpha,alpha-disubstituted alpha-amino acids.
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