4.8 Article

Photoactivated Colloidal Dockers for Cargo Transportation

Journal

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 135, Issue 43, Pages 15978-15981

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ja406090s

Keywords

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Funding

  1. MRSEC Program of the National Science Foundation [DMR-0820341]
  2. U.S. Army Research Office [W911NF-10-1-0518]
  3. NASA [NNX08AK04G]
  4. Division Of Materials Research
  5. Direct For Mathematical & Physical Scien [1105417] Funding Source: National Science Foundation
  6. NASA [NNX08AK04G, 99476] Funding Source: Federal RePORTER

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We introduce a self-propelled colloidal hematite docker that can be steered to a small particle cargo many times its size, dock, transport the cargo to a remote location, and then release it. The self-propulsion and docking are reversible and activated by visible light. The docker can be steered either by a weak uniform magnetic field or by nanoscale tracks in a textured substrate. The light-activated motion and docking originate from osmotic/phoretic particle transport in a concentration gradient of fuel, hydrogen peroxide, induced by the photocatalytic activity of the hematite. The docking mechanism is versatile and can be applied to various materials and shapes. The hematite dockers are simple single-component particles and are synthesized in bulk quantities. This system opens up new possibilities for designing complex micrometer-size factories as well as new biomimetic systems.

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