Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 135, Issue 41, Pages 15282-15285Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja407749w
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Funding
- National Science Foundation [CHE-1265491]
- National Institutes of Health [GM57014]
- MINECO [CTQ2011-24502]
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [1265491] Funding Source: National Science Foundation
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [1012270] Funding Source: National Science Foundation
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Regioselective methods for allene hydrosilylation have been developed, with regioselectivity being governed primarily by the choice of metal. Alkenylsilanes are produced via nickel catalysis with larger N-heterocyclic carbene (NHC) ligands, and allylsilanes are produced via palladium catalysis with smaller NHC ligands. These complementary methods allow either regioisomeric product to be obtained with exceptional regiocontrol.
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