Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 135, Issue 34, Pages 12536-12539Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja406025p
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Funding
- National Natural Foundation of China [21072193, 21232008]
- Ministry of Science and Technology [2011CB808600]
- Chinese Academy of Sciences
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A direct dehydrative coupling of terminal alkynes with allylic alcohols catalyzed by Pd(PPh3)(4) with an N,P-ligand assisted by Ti(OiPr)(4) has been developed. The coupling reaction tolerates various functional groups, providing a valuable synthetic tool to access 1,4-enynes.
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