Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 135, Issue 38, Pages 14012-14015Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja405919z
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Funding
- NIH-NIGMS [GM088237]
- NSF [CHE-0952753]
- DOE SCGF
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [0952753] Funding Source: National Science Foundation
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A practical, palladium-catalyzed synthesis of aryl fluorides from arylboronic acid derivatives is presented. The reaction is operationally simple and amenable to multigram-scale synthesis. Evaluation of the reaction mechanism suggests a single-electron-transfer pathway, involving a Pd(III) intermediate that has been isolated and characterized.
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