Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 135, Issue 34, Pages 12584-12587Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja407017j
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Funding
- ICIQ Foundation
- Spanish Government [CTQ2011-25418]
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Pentafluoroethane, C2F5H (HFC-125), is smoothly cuprated with preisolated or in situ-generated [K(DMF)][(t-BuO)(2)Cu] to give [K(DMF)(2)][(t-BuO)Cu(C2F5)] (1) in nearly quantitative yield. Complex 1 has been isolated, structurally characterized, and demonstrated to be an exceedingly versatile pentafluoroethylating reagent for a variety of substrates, including unactivated aryl bromides.
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