4.8 Article

Nanostar and Nanonetwork Crystals Fabricated by in Situ Nanoparticlization of Fully Conjugated Polythiophene Diblock Copolymers

Journal

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 135, Issue 47, Pages 17695-17698

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ja409206p

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Funding

  1. BRL through NRF of Korea
  2. NRF Fostering Core Leaders of the Future Basic Science Program
  3. NRF (MSIP) [2011-0014459]
  4. National Research Foundation of Korea [2012R1A1A1014680, 2011-0014459] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)

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Nanostar and nanonetwork crystals were prepared from fully conjugated poly(3-(2-ethylhexyl)-thiophene)-block-polythiophene (P3EHT-b-PT) via a simple INCP process. The structural conformation of the nanocrystals was investigated in detail, revealing that with an increase in the block length of PT, the morphology of the nanocrystals changed from nanospheres to nanorods, nanostars, and to nanonetworks.

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