Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 135, Issue 28, Pages 10183-10185Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja4046422
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Funding
- NIH [5R01GM031332-27]
- NSF CRIF:MU Award [CHE-0639094]
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The synthesis of a ruthenium complex that catalyzes Z-selective (up to 98% Z) asymmetric ring-opening/cross-metathesis with high enantioselectivity (up to 95% ee) is reported. The synthesis of the catalyst features the resolution of a chelating N-heterocyclic carbene complex by ligand substitution with a chiral carboxylate.
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