Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 135, Issue 32, Pages 11791-11794Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja407163z
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Funding
- MEXT [24109014, 24109010]
- JSPS [24.3950]
- MEXT Project of Integrated Research on Chemical Synthesis
- Grants-in-Aid for Scientific Research [24109010, 22245028, 24109014] Funding Source: KAKEN
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A novel PNP-pincer type phosphaalkene complex of iridium bearing a dearomatized pyridine unit (3) has been prepared. Complex 3 rapidly reacts with ammonia at room temperature to afford a parent amido complex in high yield. DFT calculations indicate that the phosphaalkene unit with a strong pi-accepting property effectively facilitates the N-H bond cleavage of ammonia via metal-ligand cooperation.
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