Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 135, Issue 46, Pages 17286-17289Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja409525j
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Funding
- National Science Foundation [CHE-0809642, CHE-1112195]
- Direct For Mathematical & Physical Scien [1112195] Funding Source: National Science Foundation
- Division Of Chemistry [1112195] Funding Source: National Science Foundation
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Luminescent triarylborane homo and block copolymers with well-defined chain architectures were synthesized via reversible addition fragmentation chain transfer polymerization of a vinyl-functionalized borane monomer. The Lewis acid properties of the polymers were exploited in the luminescent detection of fluoride ions. A dual-responsive fluoride sensor was developed by taking advantage of the reversible self-assembly of a PNIPAM-based amphiphilic block copolymer. Anion detection in aqueous solution was realized by introducing positively charged pyridinium moieties along the polymer chain.
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