Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 135, Issue 18, Pages 6802-6805Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja4025337
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- National Science Foundation [CHE-1213246]
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [1213246] Funding Source: National Science Foundation
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Herein we report the synthesis of pyrroloindolines via a catalytic enantioselective formal [3+2] cycloaddition of C(3)-substituted indoles. This methodology utilizes 4-aryl-1-sulfonyl-1,2,3-triazoles as carbenoid precursors and the rhodium(II)-tetracarboxylate catalyst Rh-2(S-PTAD)(4). A variety of aryl-substituted pyrroloindolines were prepared in good yields and with high levels of enantioinduction.
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