Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 135, Issue 8, Pages 2955-2958Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja312711c
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Funding
- National Basic Research Program of China [2012CB215500, 2012CB821600]
- National Natural Science Foundation of China [20825209, 21102163]
- Chinese Academy of Sciences
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An unprecedented silver-mediated vicinal trifluoromethylation-iodination of arynes that quickly introduces CF3 and I groups onto aromatic rings in a single step to give o-trifluoromethyl iodoarenes has been developed. A new reactivity of AgCF3 has been revealed, and 2,2,6,6-tetramethylpiperidine plays an important role in this difunctionalization reaction.
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