Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 135, Issue 23, Pages 8436-8439Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja404217t
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Funding
- National Basic Research Program of China (973 Program) [2012CB215306]
- 863 Program of the Ministry of Science and Technology [2012AA02A700]
- NNSFC [20972148]
- CAS [KJCX2-EW-J02]
- China Postdoctoral Science Foundation [2011M500289, 2012T50078]
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A copper-promoted trifluoromethylation reaction of aromatic amines is described. This transformation proceeds smoothly under mild conditions and exhibits good tolerance of many synthetically relevant functional groups. It provides an alternative approach for the synthesis of trifluoromethylated arenes and heteroarenes. It also constitutes a new example of the Sandmeyer reaction.
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