Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 135, Issue 29, Pages 10804-10809Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja404797y
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Funding
- NSF [CHE-0848637]
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [0848637] Funding Source: National Science Foundation
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The formation of inclusion complexes between the cucurbit[7]uril host and a cationic guest containing ferrocenylmethyl and adamantyl residues connected to an ammonium nitrogen initially leads to an similar to 1:1 mixture of two isomeric microscopic complexes, which evolves as a function of time toward the thermodynamically stable mixture, dominated by the adamantyl-included complex.
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