Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 135, Issue 36, Pages 13302-13305Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja4067833
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Funding
- Major State Basic Research Development Program [2013CB922102]
- NSFC [91022031, 21021062, 21101093]
- NSF of Jiangsu province [BK2011548]
- U.S. Department of Energy [DE-FG02-02ER45999]
- U.S. Department of Energy (DOE) [DE-FG02-02ER45999] Funding Source: U.S. Department of Energy (DOE)
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Three trinuclear Mn2Mo molecules based on the orbitally degenerate [Mo(CN)(7)](4-) anion were prepared, one of which is the first single-molecule magnet (SMM) based on heptacyanomolybdate. The blocking temperature and the energy barrier (U = 40.5 cm(-1)) are records for a cyanide-based SMM. Wide hysteresis loops and sharp quantum tunneling steps were observed from single-crystal measurements.
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