Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 134, Issue 5, Pages 2492-2495Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja2104334
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- U.S. Department of Energy, Office of Energy Efficiency and Renewable Energy
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Seven-nanometer FePt nanoparticles (NPs) were synthesized and assembled on graphene (G) by a solution-phase self-assembly method. These G/FePt NPs were a more active and durable catalyst for oxygen reduction reaction (ORR) in 0.1 M HClO4 than the same NPs or commercial Pt NPs deposited on conventional carbon support. The G/FePt NPs annealed at 100 degrees C for 1 h under Ar + 5% H-2 exhibited specific ORR activities of 1.6 mA/cm(2) at 0.512 V and 0.616 mA/cm(2) at 0.557 V (vs Ag/AgCl). As a comparison, the commercial Pt NPs (2-3 nm) had specific activities of 0.271 and 0.07 mA/cm(2) at the same potentials. The G/FePt NPs were also much more stable in the ORR condition and showed nearly no activity change after 10 000 potential sweeps. The work demonstrates that G is indeed a promising support to improve NP activity and durability for practical catalytic applications.
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