Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 134, Issue 29, Pages 11968-11970Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja305451v
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Funding
- CNRS
- Region des Pays de la Loire
- ANR-PNANO [ANR-07-NANO-030-01]
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A straightforward synthesis of a bis-(pyrrolo)tetrathiafulvalene (BPTTF)-based tetratopic ligand bearing four pyridyl units is described The first example of a TTF-based self assembled cage has been produced from this redox-active ligand through metal directed synthesis with a cis-coordinated square-planar Pt(II) complex. The resulting cage corresponds to a trigonal-prismatic structure, as shown by X-ray crystallography. A UV-vis titration indicated that the electron-rich cavity can be used to incorporate one molecule of tetrafluorotetracyano-p-quinodimethane (TCNQF(4)).
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